One-pot borylation/amination reactions: syntheses of arylamine boronate esters from halogenated arenes.
نویسندگان
چکیده
[reaction: see text] A one-pot protocol for converting 1,3- and 1,4-substituted aryl halides to arylamine boronate esters is described. This is achieved by sequential Ir-catalyzed aromatic borylation at the least hindered C-H bond of the aryl halide and subsequent Pd-catalyzed C-N coupling at the halide position of the crude arylboronic ester.
منابع مشابه
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ورودعنوان ژورنال:
- Organic letters
دوره 8 7 شماره
صفحات -
تاریخ انتشار 2006